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Method Detection Limits

POLYCYCLIC AROMATIC HYDROCARBON METHOD DETECTION LIMITS

Matrix:

Water

Sediment

Fish tissue

Oyster Tissue

Amount of Sample:

1 L

15 g

6 g

15 g

Final Extract Volume:

1ml

1ml

0.5 ml

0.5 ml

MDL (units):

(ng/L)

(ng/dry g)

(ng/wet g)

(ng/wet g)

Naphthalene

9.45

0.95

0.75

0.52

C1-Naphthalenes

7.60

0.42

1.16

2.26

C2-Naphthalenes

4.47

0.34

1.46

1.61

C3-Naphthalenes

4.47

0.34

1.46

1.61

C4-Naphthalenes

4.47

0.34

1.46

1.61

Biphenyl

2.31

0.30

0.87

0.31

Acenaphthylene

3.27

0.17

0.41

0.24

Acenaphthene

2.22

0.22

0.51

0.31

Fluorene

2.33

0.12

0.50

0.24

C1-Fluorenes

4.67

0.24

1.00

0.47

C2-Fluorenes

4.67

0.24

1.00

0.47

C3-Fluorenes

4.67

0.24

1.00

0.47

Phenanthrene

3.99

0.17

0.56

0.20

Anthracene

2.02

0.15

0.38

0.19

C1-Phenanthrenes/Anthracenes

7.98

0.34

1.12

0.40

C2-Phenanthrenes/Anthracenes

7.98

0.34

1.12

0.40

C3-Phenanthrenes/Anthracenes

7.98

0.34

1.12

0.40

C4-Phenanthrenes/Anthracenes

7.98

0.34

1.12

0.40

Dibenzothiophene

3.29

0.16

0.40

0.17

C1-Dibenzothiophenes

6.58

0.31

0.79

0.34

C2-Dibenzothiophenes

6.58

0.31

0.79

0.34

C3-Dibenzothiophenes

6.58

0.31

0.79

0.34

Fluoranthene

3.17

0.31

0.50

0.28

Pyrene

2.86

0.49

0.44

0.13

C1-Fluoranthene/Pyrene

6.34

0.61

1.00

0.56

C2-Flouranthene/Pyrene

6.34

0.61

1.00

0.56

C2-Flouranthene/Pyrene

6.34

0.61

1.00

0.56

Naphthobenzothiphene

3.99

0.17

0.56

0.20

C1-Naphthobenzothiophene

7.98

0.34

1.12

0.40

C2-Naphthobenzothiophene

7.98

0.34

1.12

0.40

C3-Naphthobenzothiophene

7.98

0.34

1.12

0.40

Benz(a)anthracene

1.15

0.18

0.21

0.24

Chrysene

1.14

0.24

0.32

0.59

C1-Chrysenes

2.28

0.48

0.65

1.18

C2-Chrysenes

2.28

0.48

0.65

1.18

C3-Chrysenes

2.28

0.48

0.65

1.18

C4-Chrysenes

2.28

0.48

0.65

1.18

Benzo(b)fluoranthene

2.25

0.26

0.69

0.26

Benzo(k)fluoranthene

3.13

0.28

0.58

0.28

Benzo(e)pyrene

3.66

0.24

0.91

0.16

Benzo(a)pyrene

3.05

0.25

0.40

0.16

Perylene

1.42

0.18

1.05

1.00

Indeno(1,2,3-c,d)pyrene

2.47

0.30

0.87

0.31

Dibenzo(a,h)anthracene

1.84

0.21

0.41

0.20

C1-Dibenzo(a,h)anthracene

3.68

0.41

0.82

0.40

C2-Dibenzo(a,h)anthracene

3.68

0.41

0.82

0.40

C3-Dibenzo(a,h)anthracene

3.68

0.41

0.82

0.40

Benzo(g,h,i)perylene

2.44

0.34

0.29

0.16

Individual Isomers

2-Methylnaphthalene

3.99

0.24

0.65

1.47

1-Methylnaphthalene

3.61

0.18

0.51

0.79

2,6-Dimethylnaphthalene

2.24

0.17

0.73

0.81

1,6,7 Trimethylnaphthalene

1.91

0.15

0.68

0.26

1-Methylphenanthrene

7.63

0.17

0.65

0.33

 

CHLORINATED HYDROCARBON METHOD DETECTION LIMITS

Matrix:

Sediment

Water

Fish Tissue

Amount of Sample:

15g dried

1 L

6 g wet

Final Extract Volume:

1 mL

1 mL

0.5 mL

MDL (units):

(ng/dry g)

(ng/L)

(ng/wet g)

Aldrin

0.07

0.64

0.45

Dieldrin

0.06

1.49

1.66

Endrin

0.06

0.72

0.91

Heptachlor

0.06

0.75

0.15

Heptachlor-Epoxide

0.08

0.64

0.60

Oxychlordane

0.07

0.29

0.91

Alpha-Chlordane

0.06

0.52

0.45

Gamma-Chlordane

0.06

0.84

0.60

Trans-Nonachlor

0.06

2.54

0.45

Cis-Nonachlor

0.07

0.63

0.15

Alpha-HCH

0.12

0.84

0.30

Beta-HCH

0.06

1.95

0.45

Delta-HCH

0.06

1.41

0.45

Gamma-HCH

0.05

0.46

0.45

2,4'-DDD

0.05

1.03

0.45

4,4'-DDD

0.08

0.59

0.45

2,4'-DDE

0.06

0.82

0.60

4,4'-DDE

0.06

0.98

0.91

2,4'-DDT

0.09

2.44

0.30

4,4'-DDT

0.06

2.44

0.91

Hexachlorobenzene

0.07

0.90

0.15

Endosulfan II

0.06

2.44

1.21

Mirex

0.07

1.77

0.30

Chlorpyrifos

0.08

0.96

0.15

PCB8/5

0.12

0.96

0.75

PCB18

0.05

0.99

0.45

PCB28

0.08

0.99

0.60

PCB29

0.06

1.12

0.45

PCB44

0.06

0.96

0.75

PCB52

0.05

1.00

0.45

PCB66/80

0.05

4.83

0.60

PCB87/115

0.09

1.00

0.60

PCB101/90

0.07

1.00

0.75

PCB105

0.08

1.24

0.30

PCB118

0.08

1.00

1.51

PCB128

0.05

1.00

3.32

PCB138/160

0.12

4.46

0.75

PCB153/132/168

0.07

0.96

1.06

PCB170/190

0.12

0.96

0.91

PCB180

0.10

0.96

0.15

PCB187

0.10

0.96

0.45

PCB195/208

0.10

0.96

0.15

PCB201/157

0.09

1.15

0.15

PCB206

0.10

1.15

0.15

PCB209

0.14

1.15

0.15

 

BUTLYTIN METHOD DETECTION LIMITS

Matrix:

Sediment

Water

Oyster Tissue

Amount of Sample:

15g dried

1 L

10 g

Final Extract Volume:

10 mL

10 mL

10 mL

MDL (units):

(ng Sn/g dry)

(ng Sn/mL)

(ng Sn/g wet)

Monobutyltin

0.224

0.010

0.174

Dibutyltin

0.292

0.012

0.539

Endrin

0.370

0.009

1.311

Tributyltin

0.434

0.007

0.763

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